Well, it took a lot of time to render, but I think I've confirmed this effect. The following is taken from HU solves, BTN can open to 2.5bb, BB can 3bet to 3x/4x/5x/6x, lots of 5bet sizes, and 6b is always all in. No rake.
100bb effective stacks seem to be in a strange "goldilocks zone" that makes extra-large 3bets especially attractive in order to force a good price on a 5b shove.
At 50bb and 75bb effective, you want to 3bet smaller as we can 5bet jam even against a min-raise. At 200bb+ we can't always get a good price on a shove, and therefore a smaller 3bet starts to become more attractive.
Detailed sim results below:
50bb effective
75bb effective
100bb effective
150bb effective
200bb effective
300bb effective
Something else I've noticed is that the BTN seems to adjust their 4bet size, such that they size down against the large/polar 3bet and size up against the smaller 3bet. Now that makes sense logically, but I also think it has to do with optimizing the 4bet size to make BB's 5bet less effective.