partypoker - 7000/14000 NL (8 max) - Holdem - 8 players
Hand converted by PokerTracker 4

BB: 45.6 BB (VPIP: 33.33, PFR: 28.57, 3Bet Preflop: 12.50, Hands: 21)
UTG: 38.51 BB (VPIP: 15.38, PFR: 8.99, 3Bet Preflop: 6.82, Hands: 91)
UTG+1: 94.64 BB (VPIP: 33.33, PFR: 33.33, 3Bet Preflop: 0.00, Hands: 3)
Hero (MP): 53.51 BB
MP+1: 30.44 BB (VPIP: 15.63, PFR: 10.00, 3Bet Preflop: 0.00, Hands: 32)
CO: 29.41 BB (VPIP: 28.89, PFR: 22.22, 3Bet Preflop: 0.00, Hands: 45)
BTN: 23.2 BB (VPIP: 22.47, PFR: 16.85, 3Bet Preflop: 9.80, Hands: 91)
SB: 12.01 BB (VPIP: 20.29, PFR: 11.94, 3Bet Preflop: 4.20, Hands: 277)

8 players post ante of 0.1 BB, SB posts SB 0.5 BB, BB posts BB 1 BB

Pre Flop: (pot: 2.3 BB) Hero has A 4

fold, fold, Hero raises to 2.2 BB, fold, CO calls 2.2 BB, fold, fold, BB calls 1.2 BB

Flop: (7.9 BB, 3 players) A T 4
BB checks, Hero bets 3.95 BB, fold, BB calls 3.95 BB

Turn: (15.8 BB, 2 players) 7
BB checks, Hero bets 10 BB, BB calls 10 BB

River: (35.8 BB, 2 players) 5
BB bets 29.35 BB and is all-in,

id fold pre. as played fold river. the question shouldn't rly be if he can have it (he could but it doesn't matter) but rather if you can have better hands to bluffcatch with. those hands could include sets, better 2p or 1p hands with a big club in it which are all better calls.

yes there is a chance

Depends what you mean by "it". The flush isn't the only threat here - he could also have a slowplayed set or better 2P (AT or rivered A5).

So to keep the math simple you're facing a roughly pot-sized bet. Do you think you're ahead 33% of the time? What worse hands can you put in villain's range here?

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Too often he does
especially at this stage in the tourney
tough decision with TT imo