Quote:
[A] the strategy calculated by PioSolver is the most profitable (long run EV wise)
No. The most exploitive strategy is and the optimal one and most exploitive offers the same payoff against optimal players but not necessarily against non-optimal players.
Against most real players there exists a strategy that wins more.
Quote:
[B] the strategy calculated by PioSolver is the one offering the lowest level of variance
There is no reason to think so (I've never tested it).
Quote:
[C] the strategy calculated by PioSolver is the one offering the highest level of variance
Nope.
Quote:
[D] the strategy calculated by PioSolver offers a low level of variance compared to the other options
[E] the strategy calculated by PioSolver offers a high level of variance compared to the other options
No, I don't know why you are focusing on variance. The optimal strategy is about EV (it guarantees that you won't lose) it doesn't offer any guarantees about variance.
Quote:
[F] deviating from the strategy calculated by PioSolver on Flop will cost me more money (long run EV wise) than doing so on the other streets (turn and river)
It's too general. It depends how big mistake you make on the flop or on the river. PioSOLVER shows you how big mistakes are (for example how much folding AA on A72r costs) so you can compare the mistakes.
Quote:
[I] it can be more profitable to deviate from the strategy calculated by Piosolver to exploit Villain's leaks
Yes.
It seems you are focusing on variance which has very little to do with how the solver works.
The solver shows you optimal strategy for both players. "Optimal" here is defined as one which guarantees the highest possible payoff no matter what your opponent does. Deviating from an optimal strategy means you are open for being exploited.
If you think about rock/paper/scissors PioSOLVER tells you to play 1/3 1/3 1/3
It a strategy that guarantees you the highest payoff across all possible opponents but it doesn't guarantee winning the most against someone who for example always plays a rock.
If you play 1 0 0 (always rock) you will not lose to optimal strategy in this toy example but you are open to being exploited by someone who plays paper a lot.
Unlike in RPS, in poker it's a bit less clearcut and many deviations from the optimal strategy cost you money even if your opponent does nothing to exploit it.