If you cannot add your Pokeroffice database, this might have two reasons.
First: The MySQL Server is not running.
To fix this, just run Pokeroffice.
Pokeroffice will start the server.
Second and mostlikely: You did not enter the correct name of the database.
The names Pokeroffice displays in his userinterface are not always the real names of the databases.
To retrieve the real name of your database go to your MySQL folder (not Pokeroffice). There you can find a subfolder named "data". All subfolders in this folder are the real names of your databases. Try to use this names or try to use this names + "_podb".
Feel free to email me at
Support@Spadeit.com so i can help you step by step in detail.