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Is the piosolver cost an annual payment or a 1 time cost to use the software indefinitely?
It's a one time cost. You can use the software indefinitely. It's likely that there will be a paid upgrade at some point. Selling lifetime upgrades doesn't make any sense business wise as there would be no incentive to work on anything new once initial sales wave dries up.
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Can you order the piosolver basic and then just pay the difference for pro or edge later if you want to upgrade?
The upgrades are the difference in prices during the first month and then the difference +25$.
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Can the scripting feature in piosolver be used to give a solution for every turn and river card if you just let it run several hours or overnight?
Pio always solves the whole tree so if you solve a tree you have a solution for every turn and river card already done. It only takes several hours on preflop trees or really huge postflop trees (you can always build a bigger one by adding more bet sizes/raise sizes).
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Is the scripting feature very user friendly? Can it usually be figured out by someone with only very limited programming experience?
We have script generation form which is easy to use. If you want to chain scripts together (solve one script, then another, then another for different betting structure) then it requires using notepad and creating a .bat file calling script one after another, I would say it's easy to figure out but may require some testing).
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Can the preflop solver be used for certain full ring situations that become heads up? For example,
Yes to all your examples.
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Well in normal sim (no script), no matter how big the pot is, final result is exploitable for 0.4XX (I put 0.5%) so not sure why in script it should be different.
It's always the same. If you look at the output from the solver on the right which looks like this:
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EV OOP: 46.839
EV IP: 53.161
OOP's MES: 47.149
IP's MES: 53.410
Exploitable for: 0.280
We translate the last value to % of the pot and display it at the bottom as "exploitable for x% of the pot".