Hey Sportstrade,
Seeing as I may have stirred this up in the CTH Backup thread, I'd be happy to help out here.
Robocopy mirror should be used with caution. This will copy any files in the source but not the destination, but will also delete any files and folders in the destination that are not in the source. This can be a good thing, if you have content that is intentionally deleted from the primary location and also wish to delete it from the backup location on sync. This can be bad if you delete a file by mistake and sync your changes to the backup location, deleting your second copy.
Make sure you are running from an Admin Command Prompt (see bottom example in the pic.
Example robocopy to copy a folder, all subfolders including empty, and redirect the logging to a textfile (on copies of many small files, redirecting the output to a log file can actually speed things up significantly because the console write speed is the limiting factor. There is the bonus of the log sticking around after you close the console window as well). I would suggest using full folder paths rather than library names, if you were using those before.
robocopy /zb /e /log+C:\robolog.txt F:\Videos G:\Videos
Robocopy can also copy to a network location on a NAS or second PC.
for example:
robocopy /zb /e /log+C:\robolog.txt F:\Videos \\myNAS\Videos
If you want this to happen on a regular schedule, you can set up a scheduled task using Windows Task Scheduler. If you want to do this on demand, you can save the robocopy string in a .cmd file and just run that when you want to sync the folders.